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Saturday, October 17, 2020 | History

2 edition of Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten. found in the catalog.

Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten.

Johannes Trudo Cornelis van Kemenade

Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten.

by Johannes Trudo Cornelis van Kemenade

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  • 29 Currently reading

Published by J. H. Pasmans in "s-Gravenhage .
Written in English

    Subjects:
  • Electron paramagnetic resonance spectroscopy.,
  • Halides.,
  • Hyperfine interactions.

  • Classifications
    LC ClassificationsQD96.E4 K45
    The Physical Object
    Pagination136 p.
    Number of Pages136
    ID Numbers
    Open LibraryOL5121063M
    LC Control Number74194460

    —, and H. G. v. Schnering: Metal-metal bonds in lower halides, oxides, and oxyhalides of heavier transition metals. Thermochemical and structural principles. Thermochemical and structural ://   Electron spin echo spectroscopy and the study of hyperfine interactions in solids. Nuclear quadrupole resonance of Bi in bismuth oxyhalides. J. Magn. Reson. Vol. 26, No. 3. P. Evidence of screening charge depression in the vicinity of chromium and manganese impurities in aluminium at low temperature. J. Phys. F: Metal

      Americium was first produced in by the group of Glenn T. Seaborg from Berkeley, California, at the Metallurgical Laboratory of the University of Chicago, a part of the Manhattan gh it is the third element in the transuranic series, it was discovered fourth, after the heavier discovery was kept secret and only released to the public in November   Tungsten–Ligand Bond Strengths for 2p Elements Including σ- and π-Bond Strength Components, A Density Functional Theory and ab Initio Study. The Journal of Physical Chemistry A , (37), DOI: /9b

    Studies of a Series of [Ni(P R 2 N Ph 2) 2 (CH 3 CN)] 2+ Complexes as Electrocatalysts for H 2 Production: Substituent Variation at the Phosphorus Atom of the P 2 N 2 Ligand. Uriah J. Kilgore, Michael P. Stewart, Monte L. Helm, William G. Dougherty, W. Scott Kassel, Mary Rakowski DuBois, Daniel L. DuBois*, and ; R. Morris Bullock* anthrapurpurin [ORG CHEM] C6H3OH(CO)2C6H2(OH)2 Orange-yellow, crystalline needles with a melting point of ⬚C; soluble in alcohol and alkalies; used in dyeing. { an⭈thrə pər⭈pə rin } anthraquinone [ORG CHEM] C6H4(CO)2C6H4 Yellow crystalline diketone that is insoluble in water; used in the manufacture of dyes. { an⭈thrə⭈kwi no¯n


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Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten by Johannes Trudo Cornelis van Kemenade Download PDF EPUB FB2

Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten II Article (PDF Available) September with 16 Reads How we measure 'reads' Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten Ligand hyperfine interactions in oxyhalides of pentavalent ().

Pagina-navigatie: Main; Save publication. Save as MODS; Export to Mendeley; Save as EndNote; Export to RefWorks; Title: Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten: Author: Van Kemenade, J.T.C.

Thesis advisor: Van Reijen, ://::uuidd46fdad1c. Download PDF: Sorry, we are unable to provide the full text but you may find it at the following location(s): (external link) Download PDF: Sorry, we are unable to provide the full text but you may find it at the following location(s): (external link); http://oai Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten II September Recueil des Travaux Chimiques des Pays-Bas Johan Van Kemenade The ligand hyperfine interaction is different for Mn substituted in CdI2 and PbI2, respectively.

Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten ://   Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten II. Recueil des Travaux Chimiques des Pays-Bas92 (10), DOI: /recl H.K.

Saha, A.K. Banerjee. Chemistry of oxometal-ions Ligand hyperfine interactions in oxyhalides of pentavalent chromium, molybdenum and tungsten II. September Johan Van Kemenade; The electron paramagnetic resonance (EPR) spectra of   The self‐consistent field Xα multiple‐scattering (SCF–MS–Xα) method has been employed to study the electronic structure Ligand hyperfine interactions in oxyhalides of pentavalent chromium (CrOCl 4) −.The principal components of the g and hyperfine interaction tensors characterizing the electron spin resonance spectra of (CrOCl 4) − have been computed using the wave functions obtained by both the SCF–MS–Xα and extended Hückel ://   Halides and Oxyhalides of the Early Transition Series and their Stability and Reactivity in Nonaqueous Media.

Ligand Hyperfine Interactions in Molybdenyl and Chromyl Halide Complexes. The Journal of Chemical Physics49 Halide Chemistry of Chromium, Molybdenum and Tungsten. , DOI: /B   Theoretical formulae for the spin-Hamiltonian (SH) parameters (g tensor g //, g ⊥ and hyperfine structure A tensor A //, A ⊥) of the ground state of oxycation MoO 3+ in [MOX 5] 2− (M=Mo 5+, Cr 4+, V 3+, X=F −, Cl − or Br −) complexes are derived by the high-order perturbation method within the frame of molecular orbital (MO) those formulae, the contributions to the SH   Single crystals of K 2 NbOF 5 H 2 O γ-irradiated at either 77 K or K and observed at K show ESR spectra centered near g =characteristic of two new paramagnetic species.

A central intense decet, which is nearly isotropic, is also the only analyzable feature of the spectrum of the polycrystalline material at K (g av =A iso (93 Nb) = (−) G). Thiagarajar College, Madurai (Academic Council, June Page 4 of THIAGARAJAR COLLEGE, MADURAI- 9 (Re-Accredited with ‘A’ Grade by NAAC)DEPARTMENT OF CHEMISTRY (For those who join in and after) Optical and EPR data were used to analyze delocalized bond structures in the antibonding and bonding states of complexes MoOL5 (L = Cl and Br).

Covalent bond parameters were calculated with consideration of charge-transfer states (CTS). The effects of CTS on the components of the g, A, and A L tensors were estimated; the third-order corrections for the EPR parameters were ://:RUCO   A detailed study of the electronic structures of a series of d1 transition metal oxohalo complexes (MOXn)m−, where M = V, Nb, Cr, Mo, and W and X = F, Cl, and Br (n = 4 or 5), has been carried out by the SCF–MS–Xα method.

The results provide values of the d–d transition energies, and also give some understanding of the similarities and differences in bonding characteristics of the   1. Introduction. Sulfite oxidase (SO), a vital molybdoenzyme found in nearly all known forms of life, catalyzes the two-electron oxidation of sulfite (SO 3 2-) to sulfate (SO 4 2-).The active site of this enzyme contains a slightly distorted square pyramidal molybdenum center, where an oxo ligand occupies the apical position and three out of four equatorial positions are occupied by sulfur   An attempt at the interpretation of the ligand hyperfine structure in the epr-spectra of mox 52⊖ -ions.

Recueil des Travaux Chimiques des Pays-Bas86 (2),   A single‐crystal ESR study has been made of K 2 NbOF 5 H 2 O γ irradiated at 77°K.

Two 93 Nb‐centered radicals were observed at 77°K; one of these is shown to be [NbOF 5] 3− with a d 1 configuration and a d xy ground state and the g, A (93 Nb), and A (19 F) tensors for this radical have been evaluated.

The A (19 F) fluorine superhyperfine interaction tensor for the equatorial   A detailed study of the electronic structures of a series of d 1 transition metal oxohalo complexes (MOX n) m−, where M = V, Nb, Cr, Mo, and W and X = F, Cl, and Br (n = 4 or 5), has been carried out by the SCF–MS–Xα method.

The results provide values of the d–d transition energies, and also give some understanding of the similarities and differences in bonding characteristics of the. To reveal structures and impurity behaviours of molybdenum and tungsten doped KTP crystals, the EPR experiments were employed, and the EPR parameters, i.e., g factors (g x, g y and g z) and hyperfine structure constants (A x, A y and A z), were measured for three orthorhombic centres, i.e., Mo 5+ centre I and W 5+ centres II and III.Molybdenum (Mo) can be used as well as a doping cation in HA.

The only paper found in this regard emphasized that Mo-HA nanorods can be used as antimicrobial agents in bone cement engineering, due to their bactericidal (S. epidermidis and E. coli) and anti-fungal (C. albicans) properties.

However, prior to being further recommended as a bone An illustration of an open book. Books. An illustration of two cells of a film strip.

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